Determination of the Vibro-Rotational Constants, the Dipole Moment’s Function and the Intensities of the HTO’s ν1 (ν3 by Usual Convention) Band

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DOI: 10.4236/jmp.2012.312243    3,292 Downloads   5,351 Views  Citations

ABSTRACT

In the first part of this paper, an analysis of the high-resolution spectrum of the HTO molecule ν1(ν3) band, from 3630 to3950 cm1, was undertaken. The rotational transition of this band was assigned using combination differences. Their wavenumbers were analyzed with a least squares fit program in order to obtain spectroscopic constants. A perturbed state has been evidenced. In the second part, with a view towards building a spectroscopic data base, a calculation of the dipolar momentum function was undertaken.

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M. Tine, D. Kobor, I. Sakho and L. Coudert, "Determination of the Vibro-Rotational Constants, the Dipole Moment’s Function and the Intensities of the HTO’s ν1 (ν3 by Usual Convention) Band," Journal of Modern Physics, Vol. 3 No. 12, 2012, pp. 1945-1957. doi: 10.4236/jmp.2012.312243.

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