Author(s)

Kaori Ishimaru, Daiki Maeda, Kaori Ono, Yuya Tanimura

Department of Chemistry, National Defense Academy, Hashirimizu, Yokosuka, Japan.

Mannich-type reactions of aldimines with silyl enolates and hetero Diels-Alder reactions of aldehydes with Danishef-sky’s diene in the presence of anion catalysts derived from proline were performed to afford the corresponding products in high yields.

Anion Catalyst; Lewis Base; Proline; Mannich-Type Reaction; Hetero Diels-Alder Reaction

K. Ishimaru, D. Maeda, K. Ono and Y. Tanimura, "Mannich-Type Reactions of Aldimines and Hetero Diels-Alder Reactions of Aldehydes Catalyzed by Anion-Type Lewis Bases Derived from a Single Molecule," International Journal of Organic Chemistry, Vol. 2 No. 3, 2012, pp. 188-193. doi: 10.4236/ijoc.2012.23028.