Biography

Prof. Georgiy B. Shul'pin

Russian Academy of Sciences, Russia


E-mail: gbsh@mail.ru


Qualifications


1975  Ph.D., Institute of Organoelement Compounds

1969  M.S., Chemistry Department of Moscow State University


Publications (selected)

  1. V. B. Romakh, B. Therrien, G. Süss-Fink, G. B. Shul’pin, "Dinuclear manganese complexes containing chiral 1,4,7-triazacyclononane-derived ligands and their catalytic potential for the oxidation of olefins, alkanes, and alcohols", Inorg. Chem., 2007, 46, No. 4, 1315–1331.
  2. G. B. Shul’pin, G. S. Mishra, L. S. Shul’pina, T. V. Strelkova, A. J. L. Pombeiro, "Oxidation of hydrocarbons with hydrogen peroxide catalyzed by maltolato vanadium complexes covalently bonded to silica gel", Catal. Commun., 2007, 8, 1516–1520.
  3. V. B. Romakh, B. Therrien, G. Süss-Fink, G. B. Shul’pin, "Synthesis, molecular structure and catalytic potential of the tetrairon complex [Fe4(N3O2-L)4(μ-O)2]4+ (L = 1-carboxymethyl-4,7-dimethyl-1,4,7-triazacyclononane)", Inorg. Chem., 2007, 46, No. 8, 3166–3175.
  4. V. B. Romakh, Y. N. Kozlov, G. Süss-Fink, G. B. Shul’pin, “The Kinetics and Mechanism of Oxidation of Isopropanol with the Hydrogen Peroxide–Vanadate Ion–Pyrazine-2-Carboxylic Acid System”, Russ. J. Phys. Chem. A, 2007, 81, No. 8, 1221–1229.
  5. Y. N. Kozlov, V. B. Romakh, A. Kitaygorodskiy, P. Buglyó, G. Süss-Fink, G. B. Shul’pin, “Oxidation of 2-Propanol and Cyclohexane by the Reagent “Hydrogen Peroxide-Vanadate Anion-Pyrazine-2-carboxylic Acid”: Kinetics and Mechanism”,J. Phys. Chem. A, 2007, 111, 7736–7752.
  6. D. Mandelli, Y. N. Kozlov, C. C. Golfeto, G. B. Shul’pin, “Peroxyacetic Acid Oxidation of Olefins and Alkanes Catalyzed by a Dinuclear Manganese(IV) Complex with 1,4,7-trimethyl-1,4,7-triazacyclononane”, Catal. Lett., 2007, 118, 22–29.
  7. G. V. Nizova, G. B. Shul’pin, “A unique rate-accelerating effect of certain amino acids in the H2O2 oxidation of alkanes catalyzed by a dinuclear manganese complex containing 1,4,7-trimethyl-1,4,7-triazacyclononane”", Tetrahedron, 2007, 63, No. 33, 7997–8001.
  8. G. B. Shul’pin, T. Sooknoi, L. S. Shulpina, “The Influence of Organic Additives on the Regioselectivity of Oxygenation of Alkanes with Hydrogen Peroxide in the Presence of TS-1 Titanium Silicalite”, Petrol. Chem., 2008, 48, No. 1, 36–39.
  9. L. S. Shul’pina, K. Takaki, T. V. Strelkova, G. B. Shul’pin, “Benzene Oxidation with Hydrogen Peroxide Catalyzed by Soluble and Heterogenized Copper Compounds”, Petrol. Chem., 2008, 48, No. 3, 219–222.
  10. V. B. Romakh, G. Süss-Fink, G. B. Shul’pin, “Vanadate Ion-Catalyzed Oxidation of Methane with Hydrogen Peroxide in an Aqueous Solution”, Petrol. Chem., 2008, 48, No. 6, 440–443.
  11. G. B. Shul’pin, D. V. Muratov, L. S. Shul’pina, A. R. Kudinov, T. V. Strelkova, P. V. Petrovskiy, “Oxygenation of aromatic hydrocarbons with hydrogen peroxide catalyzed by rhodium carbonyl complexes”, Appl. Organometal. Chem., 2008, 22, 684–688.
  12. G. B. Shul’pin, M. V. Kirillova, T. Sooknoi, A. J. L. Pombeiro, “Oxidation of Saturated Hydrocarbons to Alkyl Hydroperoxides by a ‘H2O2/Titanosilicalite-1/NaOH/MeCN’ System”, Catal. Lett. 2008, 128, 135–141.
  13. D. Mandelli, K. C. Chiacchio, Y. N. Kozlov, G. B. Shul’pin, “Hydroperoxidation of alkanes with hydrogen peroxide catalyzed by aluminium nitrate in acetonitrile”, Tetrahedron Lett., 2008, 49, 6693–6697.
  14. Y. N. Kozlov, G. V. Nizova, G. B. Shul’pin, “Alkane oxidation by the system ‘tert-butyl hydroperoxide–[Mn2L2O3][PF6]2 (L = 1,4,7-trimethyl-1,4,7-triazacyclononane)–carboxylic acid’, J. Phys. Org. Chem., 2008, 21, 119–126.
  15. G. B. Shul’pin, M. G. Matthes, V. B. Romakh, M. I. F. Barbosa, J. L. T. Aoyagi, D. Mandelli, “Oxidations by the system ‘hydrogen peroxide–[Mn2L2O3][PF6]2 (L = 1,4,7-trimethyl-1,4,7-triazacyclononane)–carboxylic acid’. Part 10: Co-catalytic effect of different carboxylic acids in the oxidation of cyclohexane, cyclohexanol, and acetone”, Tetrahedron, 2008, 64, 2143–2152.
  16. G. B. Shul’pin, Y. N. Kozlov, S. N. Kholuiskaya, M. I. Plieva, “Oxidations by the system ‘hydrogen peroxide–[Mn2L2O3]2+ (L = 1,4,7-trimethyl-1,4,7-triazacyclononane)–oxalic acid’. Part 11. Degradation of dye Rhodamine 6G and oxygenation of cyclohexene”, J. Mol. Catal. A: Chem., 2009, 299, 77–87.
  17. L. S. Shul’pina, M. V. Kirillova, A. J. L. Pombeiro, G. B. Shul’pin, “Alkane oxidation by the H2O2–NaVO3–H2SO4 system in acetonitrile and water”, Tetrahedron, 2009, 65, 2424–2429.
  18. D. Mandelli, A. C. N. do Amaral, Y. N. Kozlov, L. S. Shul’pina, A. J. Bonon, W. A. Carvalho, G. B. Shul’pin, “Hydrogen Peroxide Oxygenation of Saturated and Unsaturated Hydrocarbons Catalyzed by Montmorillonite or Aluminum Oxide”,Catal. Lett., 2009, 132, 235–243.
  19. J. Bonon, D. Mandelli, O. A. Kholdeeva, M. V. Barmatova, Y. N. Kozlov, G. B. Shul’pin, “Oxidation of alkanes and olefins with hydrogen peroxide in acetonitrile solution catalyzed by a mesoporous titanium-silicate Ti-MMM-2”, Appl. Catal. A: General, 2009, 365, 96–104.
  20. M. V. Kirillova, M. L. Kuznetsov, V. B. Romakh, L. S. Shul’pina, J. J. R. Fraústo da Silva, A. J. L. Pombeiro, G. B. Shul’pin, “Mechanism of oxidations with H2O2 catalyzed by vanadate anion or oxovanadium(V) triethanolaminate(vanadatrane) in combination with pyrazine-2-carboxylic acid (PCA): Kinetic and DFT studies”, J. Catal., 2009, 267, 140–157.
  21. M. V. Kirillova, Y. N. Kozlov, L. S. Shul’pina, O. Y. Lyakin, A. M. Kirillov, E. P. Talsi, A. J. L. Pombeiro, G. B. Shul’pin, “Remarkably fast oxidation of alkanes by hydrogen peroxide catalyzed by a tetracopper(II) triethanolaminate complex: Promoting effects of acid co-catalysts and water, kinetic and mechanistic features”, J. Catal., 2009, 268, 26–38.
  22. G. B. Shul’pin, Y. N. Kozlov, L. S. Shul’pina, A. R. Kudinov, D. Mandelli, “Extremely Efficient Alkane Oxidation by a New Catalytic Reagent H2O2/Os3(CO)12/Pyridine”, Inorg. Chem., 2009, 48, No. 22, 10480–10482.
  23. G. B. Shul’pin, Y. N. Kozlov, L. S. Shul’pina, P. V. Petrovskiy, “Oxidation of alkanes and alcohols with hydrogen peroxide catalyzed by complex Os3(CO)10(mu-H)2”, Appl. Organometal. Chem., 2010, 24, 464–472.
  24. M. V. Kirillova, A. M. Kirillov, D. Mandelli, W. A. Carvalho, A. J. L. Pombeiro, G. B. Shul’pin, ”Mild homogeneous oxidation of alkanes and alcohols including glycerol with tert-butyl hydroperoxide catalyzed by a tetracopper(II) complex”, J. Catal., 2010, 272, 9–17.
  25. G. B. Shul’pin, Y. N. Kozlov, L. S. Shul’pina, T. V. Strelkova, D. Mandelli, “Oxidation of Reactive Alcohols with Hydrogen Peroxide Catalyzed by Manganese Complexes” , Catal. Lett., 2010, 138, No. 3–4, 193–204.
  26. Y. N. Kozlov, L. S. Shul’pina, T. V. Strelkova, G. B. Shul’pin, “Kinetics and Mechanism of 1-Phenylethanol Oxidation by the System Hydrogen Peroxide–Manganes(IV) Binuclear Complex–Oxalic Acid”, Russ. J. Phys. Chem. A, 2010, 84, No. 9, 1502–1505.
  27. G. B. Shul’pin, M. V. Kirillova, Y. N. Kozlov, L. S. Shul’pina, A. R. Kudinov, A. J. L. Pombeiro, “Decamethylosmocene-catalyzed efficient oxidation of saturated and aromatic hydrocarbons and alcohols with hydrogen peroxide in the presence of pyridine”, J. Catal., 2011, 277, No. 2, 164-172. DOI: 10.1016/j.jcat.2010.11.002

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